|
|
cis-1,4-polyisoprene + O2 <=> (4Z,8Z)-4,8-dimethyl-12-oxotrideca-4,8-dienal
|
1.13.11.85
exo-cleaving rubber dioxygenase
1.13.11.87
endo-cleaving rubber dioxygenase
|
–
–
|
M
|
| |
BRENDA:
BR52345;
BS445822
KEGG:
R11999
MetaCyc:
RXN-19029
|
|
|
|
n isopentenyl_diphosphate <=> cis-1,4-polyisoprene + n diphosphate
|
2.5.1.20
rubber cis-polyprenylcistransferase
|
–
|
K
|
| |
KEGG:
R03917
|
|
|
|
cis-1,4-polyisoprene + O2 <=> (4Z,8Z,12Z,16Z,20Z,24Z)-4,8,12,16,20,24-hexamethyl-28-oxononacosa-4,8,12,16,20,24-hexaenal + (4Z,8Z,12Z,16Z,20Z)-4,8,12,16,20-pentamethyl-24-oxopentacosa-4,8,12,16,20-pentaenal + (4Z,8Z,12Z,16Z)-4,8,12,16-tetramethyl-20-oxohenicosa-4,8,12,16-tetraenal + (4Z,8Z,12Z)-4,8,12-trimethyl-16-oxoheptadeca-4,8,12-trienal
|
1.13.11.87
endo-cleaving rubber dioxygenase
|
–
|
M
|
| |
MetaCyc:
RXN-19030
|
|
|
|
isopentenyl_diphosphate + cis-1,4-polyisoprene <=> cis-1,4-polyisoprene + diphosphate
|
2.5.1.20
rubber cis-polyprenylcistransferase
|
–
|
M
|
| |
MetaCyc:
RXN-9137
|
|
|
|
isopentenyl_diphosphate + cis-1,4-polyisoprene <=> diphosphate + cis-1,4-polyisoprene + (2Z,6Z)-farnesyl_diphosphate
|
2.5.1.20
rubber cis-polyprenylcistransferase
|
–
|
|
| |
BRENDA:
BS410877
|
|
|
|
isopentenyl_diphosphate + cis-1,4-polyisoprene <=> diphosphate + (2Z,6Z)-farnesyl_diphosphate
|
2.5.1.20
rubber cis-polyprenylcistransferase
|
–
|
|
| |
BRENDA:
BS355473
|
|
|
|
cis-1,4-polyisoprene + n O2 <=> tetra-C20_and_higher_oligo-isoprenoids_with_aldehyde_and_keto_end_groups
|
1.13.99.B1
|
–
|
|
| |
BRENDA:
BR52492
|
|
|
|
isopentenyl_diphosphate + (2E,6E)-farnesyl_diphosphate + cis-1,4-polyisoprene <=> diphosphate + (2Z,6Z)-farnesyl_diphosphate
|
2.5.1.20
rubber cis-polyprenylcistransferase
|
–
|
|
| |
BRENDA:
BS355475
|
|
